Role of contact work function, back surface field, and. Controllable multinary alloy electrodeposition for thin. The fabricated solar cell with s1 and s2 absorbers showed significant. The sandwichtype solar cell was assembled by placing the czts ce on the n719 dyesensitized photoelectrode working electrode and clipped together as an open cell for measurements. Effect of absorber parameters on znsczts based solar cell effect of czts thickness. Efficiency enhancement of cu2znsns4 thin film solar cells. Czts solar cells have achieved comparitively low record ef. Although the dark are degraded with respect to the cztsse cell see main text, ff of the cztsse cell despite its lower voc. Copper zinc tin sulfide based thin film solar cells. Cu2znsns4 czts is a promising candidate material for photovoltaic applications. Czts solar cell device simulation with varying absorber thickness. Cu 2znsns 4 czts, having the kesterite structure, is one of the most promising absorber layer candidates for low cost thin film solar cells. Role of contact work function, back surface field and. Various types of solar cell technologies and current trends of development 2 16.
Electrodeposition ed technology is a lowcost industrial candidate for solar cell fabrication. A solar cell, or photovoltaic cell in very early days also termed solar battery a denotation which nowadays has a totally different meaning, see here, is an electrical device that converts the energy of light directly into electricity by the photovoltaic effect, which is a physical and chemical phenomenon. Cu2znsns4 czts is considered to be one of the most promising light absorbing materials for lowcost and highefficiency thinfilm solar cells. Synthesis and characterization of kesterite cu2znsns4. However, there is still a need to develop lowcost and scalable synthesis methods. Thinfilm solar cells are commercially used in several technologies, including cadmium telluride cdte, copper indium gallium diselenide cigs, and amorphous thinfilm silicon asi, tfsi. Exploring cdfree buffer layer for czts photocathode for. Molybdenum mo thin films are widely used as a back contact for photovoltaic devices such as cuin 1. Impact of excess and disordred sn sites on cu2znsns4 absorber. The application of kesterite in solar cells has attracted con. In this final report highlights of the first three quarters will be provided and details will be given of the final quarter. However, despite the efforts and developments undertaken in recent years, the czts thin film solar cell efficiency is still far from the maximum theoretical efficiency.
An overview of solar cell technology mike mcgehee materials science and engineering global climate and energy projectglobal climate and energy project center for advanced molecular photovoltaics precourt institute stanford university konarka nanosolar john benner provided the slides with the nrel logo. Today, energy is the key element of modern development 1. The maximum efficiency reported for mixed sulfoselenide cztsse cell is 12. We determined the electrical junction ej locations in cuin,gase 2 cigs and cu 2 znsnse 4 czts solar cells with 20. Pss for stable and efficient inverted perovskite solar cells. An alternative route towards lowcost cu2znsns4 thin film. Czts solar cell s and s elements individual and combined s. Copper zinc tin sulfide czts is a quaternary semiconducting compound which has received.
Czts is comprised of earth abundant and nontoxic elements, and power conversion efficiencies in czts based solar cells have risen quickly. Read czts absorber layer for thin film solar cells from electrodeposited metallic stacked precursors zncusn, applied surface science on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at your fingertips. The material is composed of nontoxic and earthabundant constituents, has optical properties suitable for photovoltaic application, and can be synthesized using a wide variety of methods. Publishers pdf, also known as version of record link back to dtu orbit citation apa. Surfactantfree czts nanoparticles as building blocks for. The most promising result is the compound cu 2 znsns 4 czts, which is now a recognized potential material for the absorber layer in photovoltaic applications. The characterization methods consist of various optical and electrical measurements on solar cells in steadystate, transient and frequency domain. It was confirmed that czts solar cells with high conversion efficiency existed in a relatively narrow composition region.
Uppsala university, disciplinary domain of science and technology, technology, department of engineering sciences, solid state electronics. However, the practical aspects of controlling deposit morphology and composition have not been significantly addressed because of the complex coplating variables that still need to be understood for multinary alloy ed. Abstracta nonvacuum and lowcost route to fabrication of cu2znsns4 czts thin film as absorber layer for thin film solar cell is demonstrated. Characteristics of insubstituted czts thin film and. The influence of the composition ratio on cztsbased thin. We have utilized multivalent defects in the bulk of czts absorber layer to match our baseline solar cell to the experimentally reported czts solar cell 22.
Wurtzite copperzinctin sulfide as a superior counter. Characterization of a czts thin film solar cell grown by. Copper zinc tin sulfide cu2znsns4 or czts is a promising candidate as a sunlight absorbing layer in thin film solar cells. The back contact is the first layer to be deposited and its properties have significant effects on the solar cell performance. It is composed of earth abundant, nontoxic elements. Czts was first created in 1966 and was later shown to exhibit the photovoltaic effect in 1988. Pdf effect of czts parameters on photovoltaic solar cell from. Zinc tin oxide zto is a potential buffer layer for the czts photocathode as it has shown to be a good interface with czts and such cztszto solar cells have shown comparable efficiencies with the cztscds solar cells. Beginning with an overview and historical background of copper zinc tin sulphide czts technology, subsequent chapters cover properties of czts thin films, different preparation methods of czts thin films, a comparative study of czts and cigs solar cell, computational approach, and future applications of czts thin film solar modules to both groundmount and rooftop installation. In the present study, wurtzite czts nanocone has been synthesized by a green chemistry route. Silvaco simulating solar cell devices using silvaco tcad. Cts and czts for solar cells by pulsed laser deposition and pulsed electron deposition rebecca bolt ettlinger november 14, 2016 phd thesis supervisor. Temperature dependence of the open circuit voltage voc dominant carrier recombination mechanism can be obtained from the open circuit voltage vs.
Click download or read online button to get copper sun book now. In this paper, the fabrication method of cztsbased thin film solar cells in our laboratory was stated briefly and the influence of the composition ratio on the photovoltaic properties were presented. Light shining on the solar cell produces both a current and a voltage to generate electric power. Each of the first three quarters of the subcontract has been detailed in quarterly reports. Wurtzite czts could be considered as the derivative of wurtzite zns. In this study10, a citrate complex system was used to fabricate czts on glassftozns, for the fabrication of thin film solar cells the surface. Vacuum deposited copper zinc tin sulfide czts thin film. Synthesis, deposition, and microstructure development of.
In the czts study, kesterite is the form generally used and is easy to synthesize, which includes a tetragonal cell crystal 15, 18, 37. Materials for renewable and sustainable energy, apr 2017. Effect of absorber parameters on zns czts based solar cell effect of czts thickness. An overview of solar cell technology mike mcgehee materials science and engineering global climate and energy projectglobal climate and energy project center for advanced molecular photovoltaics precourt institute stanford university konarka nanosolar. The quaternary compound cu2znsns4 czts gained considerable attention in the last decade due to its potential as an activelayer semiconductor for lowcost thinfilm solar cells. Pdf characterization of a czts thin film solar cell grown by. Characterization of a czts thin film solar cell grown by sputtering. We showed the applicability of these nanocrystal coatings for thin film solar cells by demonstrating a czts thin film solar cell using coatings annealed in a sulfur atmosphere. Impact of molybdenum out diffusion and interface quality. In this simulation, the czts thickness was varied from 0. We report the performance of cu2znsns4 czts thin film solar cell that showed efficiency in the.
Performance of cztsmapbi 3 solar cells remarkably depends on czts film thickness czts film thinner than 100 nm is a more effective htm in cztsmapbi 3 solar cells czts is better than pedot. Traditional siliconbased solar cells use crystalline silicon produced with heavy equipment, making the sibased solar cells relatively expensive. Development and characterization of copper zinc tin. Czts absorber layer for thin film solar cells from.
A solar cell is an electronic device which directly converts sunlight into electricity. The synthesis and characterization of thin film copper. Study of czts and cztsse solar cells for buffer layers. Optimization of mocr bilayer back contacts for thinfilm. The process involves synthesis of cuznsn composite oxide nanoparticles, preparation of composite oxide ink, deposition of composite oxide thin film and subsequent sulfurization treatment. In the present contribution a znocdsczts structure with new thicknesses of the different layers has been proposed using solar cell capacitance simulator. We performed centrifugation to screen the asmilled czts and obtain nanocrystals. The development of a cuznsns czts based low cost solar cell to make a device by creating advanced material. Fabrication of thin film czts solar cells with pulsed. An overview of solar cell technology stanford university. Their findings reported stoichiometric composition of czts with the usage of citrate for electrodeposition.
Silvaco tcad offers complete and well integrated simulation software for all aspects of solar cell technology. Wurtzite copperzinctin sulfide as a superior counter electrode material for dyesensitized solar cells. The crystal cell kesterite czts is analogous to the vertical enlarged binary zincblende zns. Comprehensive characterization and modelling of operation. Read a mild hydrothermal route to synthesis of czts nanoparticle inks for solar cell applications, physica status solidi c current topics in solid state physics on deepdyve, the largest online rental service for scholarly research with thousands of academic publications available at. This site is like a library, use search box in the widget to get ebook that you want. The absorber layer thickness is a crucial parameter on the performance of thin film solar cells. Czts is a compound semiconductor that uses earthabundant elements.
Improvement of mocu2znsns4 interface for cu2znsns4 czts. We conducted a systematic study of the factors controlling crystal growth and microstructure development during sulfidation annealing of films cast from colloidal. Scaps has been used to simulate multivalent defect occurring in chalcopyrite and chalcogenide solar cell materials. The possible future prospects in the performance improvement of the czts based solar cell is analyzed in the present work with the. The developed simulation software solves the coupled.
Cigs and cdte are two of the most promising thinfilm solar cells and have recently seen growing. Cu2znsns4 czts is a prominent low cost absorber layer to be used as a substitute of cigs absorber layer in the thin film solar cells. The exponential decay of the photovoltage with respect to time directly represents the faster. Effect of calcination temperature on the properties of. Effect of calcination temperature on the properties of czts absorber layer prepared by rf sputtering for solar cell applications.
If you continue browsing the site, you agree to the use of cookies on this website. A thinfilm solar cell is a second generation solar cell that is made by depositing one or more thin layers, or thin film tf of photovoltaic material on a substrate, such as glass, plastic or metal. Polycrystalline silicon solar cell polysi or mcsi polycrystalline pv modules are generally composed of a number of different crystals, coupled to one another in. Spisces, blaze, luminous, tft, device3d, luminous3d and tft3d 1. Fabrication of cu2znsns4 czts nanoparticle inks for. Improvement of mocu2znsns4 interface for cu2znsns4 czts thin film solar cell application volume 1638 hongtao cui, xiaolei liu, xiaojing hao, fangyang liu, ning song, wei li, chang yan, gavin conibeer, martin green. Pdf on jan 28, 2019, abdellah benami and others published effect of czts parameters on photovoltaic solar cell from numerical. The solar cell efficiency in czts was increased to 5. The benefits of czts include the abundant and inexpensive sup. Tcad modules required for solar cell simulation include.
A process route for the fabrication of solventredispersible, surfactantfree cu2znsns4 czts nanoparticles has been designed with the objective to have the benefit of a simple sulfide source which advantageously acts as i a complexing agent inhibiting crystallite growth, ii a surface additive providing redispersion in low ionic strength polar solvents and iii a transient. Effect of czts parameters on photovoltaic solar cell from. In this work, we fabricated czts nanocrystal inks by a wet ball milling method, with the use of only nontoxic solvents, followed by filtration. The surface recombination velocity srv used at left contact are 105 cms for electron and 107 cms for. Cu 2 znsns 4 czts based devices has become increasingly popular due to the better efficiency with different architectures for various types of solar cells. Figure 3 shows tpv characteristics of the czts solar cell and estimated carrier lifetime plots. Cu2znsns4 czts, having the kesterite structure, is one of the most promising absorber layer candidates for low cost thin film solar cells, because of its suitable.
Peter uhd jepsen dtu fotonik, ecthnical university of denmark 1. Major problems in czts where tsm can help 1 why is the voc low. Green synthesis of wurtzite copper zinc tin sulfide. Simulating solar cell devices using silvaco tcad tools. Solutionprocessed czts film is insitu synthesized on ito substrate compact czts thin film consists of about 1020 nm nanoparticles. Characteristics of insubstituted czts thin film and bifacial solar cell jie ge,a, b, c, junhao chu,a, b, c jinchun jiang,b yanfa yan, and pingxiong yanga a key laboratory of polar materials and devices ministry of education, east china normal university, shanghai 200241, china.
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